It might be suggested that capillary action is the heart and life of the tree. ![]() Assisting the process is the input of water via the roots, and the transpiration of moisture through the leaves. The song goes, “I think I shall never see, a poem lovely as a tree.” A tree contains tiny capillary tubes that transport moisture and nutrients. Mercury does not exhibit capillary action. Hence, mercury atoms do not adhere to glass. While mercury liquid exhibits cohesion for other mercury atoms, it does not have a net charge, nor does it form hydrogen bonds. This attraction or pulling together is the source of water’s cohesive character. Water molecules attract each other, as well as any other nearby charged atoms or molecules. That means they behave much as a magnet does, with its north and south poles. The positive charge of the hydrogen atoms is concentrated on one side of the lone oxygen atom, while the other side of the oxygen maintains a slight negative charge. Hydrogen BondsĪs discussed at length in the article The Dipolar Molecule Water, water (H₂O) is not a straight molecule, but is shaped like a mouse’s head. ![]() The hydrogen bonds counter part of the gravity exerted on the water in the tube, much as the ant bridge resists the weight of the ants crossing over it.įigure 3. These bonds are weaker than ordinary chemical bonds, yet they behave much like weak springs pulling the molecules together and up (thus successfully countering gravity).įigure 3 pictures the hydrogen bond connections between water molecules. Water accomplishes this via hydrogen bonding. To achieve this, the ants must pull together. The best bridge is a straight bridge, not a sagging bridge. The bridge is constructed, the majority cross over, the bridge is disassembled. Sometimes they may create an ant “bridge” to cross a gap. To get a better understanding of cohesion, consider a colony of ants. The thinner the tube is, the less gravity can counter these forces. Interestingly, the thinner the tube, the greater is the ratio of the force of adhesion to cohesion and gravity. This forces us to recognize a second force at work – cohesion. While we have alluded to the way water adheres to glass and forms a concave meniscus, we have not discussed why water rises up the tube to form an elevated column above the level of the supply vessel. ![]() Nevertheless, one force both water and mercury share in common is cohesion.Ī very detailed atomic-level discussion that explains why water adhesion to glass is greater even than cohesion of water molecules and is the controlling factor in capillary action, is skillfully explained in this Khan Academy Video… It fills the tube to just below the level of the supply with a slightly convex shape in the middle of the tube. In fact, water molecules bond more tightly to glass than they do to each other. Water adheres to the glass walls even when there is no body of liquid to support it.¹ This is because it forms hydrogen bonds with the glass, since glass is constructed from oxygen-rich polar silicon dioxide SiO₂ molecules. Three forces are responsible for the behavior of the liquids – adhesion, cohesion, and gravity. It forms what looks like the upper portion of a sphere – a convex meniscus. The water rises up its tube and forms a concave meniscus at top. Two capillary tubes (not drawn to scale) are immersed in liquid – the left tube in water, the right in mercury. The liquids we will discuss as examples are water and mercury. A capillary is a tube with a fine bore, typically less than a millimeter.įor the purpose of our discussion, we will use a scientist’s glass capillary tube, which is both straight and clear. What is capillary action? The easiest way to define it is to give the simplest example of it at work.
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